Upcycling solar panels into thermoelectrics
A team of scientists from the Agency for Science, Technology and Research (A*STAR) and Nanyang Technological University, Singapore (NTU Singapore) has developed technology that can turn old solar panels into a high-performance, energy-harvesting thermoelectric material that harvests heat and converts it into electricity. The joint study was published in the scientific journal Advanced Materials in March 2022.
With the increased use of solar renewable energy over the last few decades, and a limited lifespan of 30 years for solar panels, the global waste generated from silicon in end-of-life solar panels is projected to hit 8 million tonnes by 2030 and 80 million tonnes by 20501.
Solar panels are made up of solar cells, which contain a complex mix of various materials such as aluminium, copper, silver, lead, plastic and silicon. Separating such materials and recycling them each in a unique way is a complex and costly process; therefore, current recycling approaches mainly recover only the glass and metallic support structures from solar panels.
Silicon, which makes up 90% of solar cells, normally ends up in landfills. It is challenging to upcycle silicon as recycled silicon has impurities and defects, which cannot be used to create functional solar cells. This makes it difficult to recycle used silicon into solar cells or other silicon-based technologies.
The joint team turned this limitation into opportunity by developing technology to transform expired solar cells into enhanced thermoelectric material. Compared to solar cells, this technology capitalises on the contrasting properties of thermoelectrics, where the incorporation of impurities and defects serves to enhance rather than diminish their performance.
Scientists from A*STAR’s Institute of Materials Research and Engineering (IMRE) and Institute of High Performance Computing (IHPC), led by Dr Ady Suwardi, Deputy Head of the Soft Materials research department at IMRE, contributed their expertise in material properties and computational modelling, respectively, to determine the optimal composition of materials.
Scientists from NTU’s Singapore-CEA Alliance for Research in Circular Economy (SCARCE), led by Associate Professor Nripan Mathews, leveraged their expertise in extracting valuable materials from solar waste to develop the technologies required for recovery of silicon from solar panel waste.
To impart thermoelectric characteristics such as power conversion and cooling efficiency to waste silicon and to enhance the performance of the upcycled silicon-based thermoelectrics, the team first pulverised solar cells into fine powder using ball milling technology. Next, phosphorus and germanium powder were added to alter their original properties before the powder combination was processed under high heat and temperature using spark plasma sintering.
After evaluating the electrical property of various combinations, the team achieved a sample offering the most optimised thermoelectric performance, with a thermoelectric figure of merit (zT) of 0.45 at 873 K — the highest amongst elemental silicon thermoelectrics.
“This study demonstrates that thermoelectrics is a fertile ground for upcycling defect- and impurity-sensitive semiconductors,” said Suwardi.
“Our goal is to create sustainable materials, extend the life cycle of various products and reduce waste to cultivate a circular economy, and we can only do this through partnership with institutes of higher learning and other collaborators from the local R&D ecosystem,” added IMRE scientist Dr Jing Wu, who was co-corresponding author of the paper together with Suwardi.
This effort highlighted the intertwined research by SCARCE whereby silicon recovered from solar panel waste is being upcycled by A*STAR into silicon-based thermoelectrics for harvesting of electricity from heat. The team will also look to pilot the technology for large-scale upcycling of waste silicon, which can be used for high-temperature energy-harvesting applications such as converting heat generated from industrial waste processes into electricity.
1. G. A. Heath, T. J. Silverman, M. Kempe, M. Deceglie, D. Ravikumar, T. Remo, H. Cui, P. Sinha, C. Libby, S. Shaw, Nat. Energy 2020, 5, 502.
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